UNDERSTANDING
PLASTICS
In the last 25 years, the use of thermoplastics in the valve industry has grown steadily. Early applications were limited to check balls,
seals and decorative caps. The timing of when the first plastic valve
was introduced is an issue of debate,
but here is my own personal experience, and it illustrates the strengths
and weaknesses of certain plastics:
When I was seven, my parents
gave me a Coca-Cola dispensing
machine. The machine consisted of a
red plastic base with a mount to hold
a bottle, which, because it was the
1960s, was made of glass.
The top of the unit had a white
plastic cover with the trademark
logo, a plastic handle and a small
plastic valve. After opening the cola
bottle, you slid the valve over the top
and laid that bottle on its side in the
base. The valve slipped through an
opening that provided push-button
function. Of course, this plastic valve
suffered the effects of long-term use
and chemical exposure, and it still
retains the masking tape I placed on
it in the 60s to stop a leak. More
than likely, a hoop stress failure was
the culprit.
Although I didn’t evaluate these
aforementioned valves to determine
their material composition, it’s a
safe bet they were made from widely
available commodity plastics including polystyrene and polyolefin-based
HIGH-PERFORMING ENGINEERING
THERMOPLASTICS HAVE MADE STRONG
INROADS INTO THE VALVE MARKET AND
WILL CONTINUE TO DO SO BECAUSE OF
THEIR HIGH STRENGTH, LIGHT WEIGHT
AND CORROSION RESISTANCE.
BY PATRICK NEEL
materials. While functional, these materials are more limited by temperature,
mechanical performance and pressure than engineering-grade plastics.
While this is only my own experience, it brings up a point about plastics
grades. Specifically, the limited property profile of commodity plastics in the
valve market has left a sizeable window of opportunity for higher-performing
plastics, namely engineering materials. These products afford higher
temperature performance, greater chemical resistance and more strength (see
Figure 1).
Because of this broader performance portfolio, the use of engineering plastics
has grown over the years. For example, one of the first polymers in the valve
industry was polytetrafluoroethylene (PTFE), which was used for soft-seated ball
valves. Today, engineering plastics such as nylon (PA), polysulfone (PSU) and
polyetheretherketone (PEEK) can be found in many check valves, medical
valves, beverage dispenser valves, ball valves, quarter-turn valves, diaphragm
valves, seals, check rings and bushings.
What’s more, valve suppliers are increasingly considering plastics as a
replacement for brass in quarter-turn valves. For example, a Midwest
manufacturer of valves and components for the plumbing industry uses
unreinforced polyphenylsulfone (PPSU) because of its light-weight strength,
corrosion resistance and ability to withstand prolonged exposure to hot,
chlorinated water. This lead-free plastic alternative eliminates mineral build-up
and is about 75% lighter than brass. Another key advantage is the ease of
installation of PPSU compared to brass. The injection-molded quarter-turn
valves offer quick connect or crimp-style connectivity, which speeds up
installation and eliminates the need for brazing.
Figure 1. Key properties of engineering plastics vs. metals
33% glass- 30% glass-filled aromatic filled
Property Units nylon polysulfone
Tensile strength Ksi 32,000 15,600
Tensile elongation break 2. 5 2
Specificgravity g/cm3 1. 48 1. 49
Specific strength* 21,622 10,470
*Specific strength is the tensile strength divided by the specific gravity
30% glass-
filled
PEEK
22,900
2. 7
1.53
14,967
Leaded tin
Bronze
C92200
34,000
24
8.64
3,935
Stainless
Steel 316
78,000
54
7.85
9,936